上海基础房价相关指标及走势的分析与研究

基础房价的相关指标及其走势一直是大众关心的热门话题．本文通过对上海基础房价相关指标的分析，建立了市场房价走势的两个数学模型．模型一：在相关性分析的基础上利用主成分分析消除指标间的共线性，再用回归拟合房价模型并进行预测；模型二：在相关性分析的基础上利用核估计方法预测出房价．继呵对2005年下半年的房价走势进行了预测，得出的结果与实际情况相吻合．     

Hypersurface with Constant Main Curvature Symmetric Functions

ＨｙｐｅｒｓｕｒｆａｃｅｗｉｔｈＣｏｎｓｔａｎｔＭａｉｎＣｕｒｖａｔｕｒｅＳｙｍｍｅｔｒｉｃＦｕｎｃｔｉｏｎｓ￥ＷｕＢａｏｑｉａｎｇ；ＳｏｎｇＨｏｎｇｚａｏ（ＸｕｚｈｏｕＴｅａｃｈｅｒｓＣｏｌｌｅｇｅ，２２１００９）（ＨｅｎａｎＵｎｉｖｅｒｓｉｔｙ，...     

Scale functions on $p$-adic Lie groups

Let G be a p-adic Lie group. Then G is a locally compact, totally disconnected group, to which Willis [14] associates its scale function G : G→ℕ. We show that s can be computed on the Lie algebra level. The image of s consists of powers of p. If G is a linear algebraic group over ℚ _p , s(x)=s(h) is determined by the semisimple part h of x∈G. For every finite extension K of ℚ _p , the scale functions of G and H:=G(K) are related by s _H ∣ _G =s _G ^{[ K :ℚ} _p ^]. More generally, we clarify the relations between the scale function of a p-adic Lie group and the scale functions of its closed subgroups and Hausdorff quotients. Received: 20 February 1997; Revised version: 18 May 1998     

α—氨基酸的快原子轰击质谱

本文研究了１８种α－氨基酸的快原子轰击质谱，发现添加三氟乙酸溶液能显著提高灵敏度，改善谱图。特征碎片主要有中性丢失ＣＯ２Ｈ２，Ｈ２Ｏ，ＮＨ３的离子以及Ｒ＾＋离子。侧链的性质决定了碎片的产生和离子的强弱。     

一种新型联萘基旋光共轭聚合物的圆二色谱和圆偏振荧光光谱

众所周知 ,聚合物的光电性质依赖于聚合物链的构象和 (或 )组成 ,通过在聚合物上引入手性单元 ,采用圆二色谱 ( CD)和圆偏振荧光光谱 ( CPL)等方法可表征聚合物结构 [1] .近年来 ,由于圆偏振光可用作光数据存储和液晶显示器背景光 [2 ] ,人们开始注重共轭聚合物圆偏振光材料的研究 .共轭聚合物的光致和电致圆偏振光的现象由一种带手性侧链的聚噻吩[3 ] 和一种带手性侧链的聚 (对苯撑乙烯 ) [4 ]产生 ,但它们的圆偏振荧光度 (用不对称因子 glum=2 ( IL-IR) / ( IL+IR)表示 ,IL 和 IR 分别指左圆偏振光强度和右圆偏振光强度 )相对较低 …     

Liquid crystalline ionomers. II. Main chain liquid crystalline polymers with terminal sulfonate groups

Liquid crystalline ionomers containing sulfonate groups on the terminal unit of the chain were synthesized by an interfacial condensation reaction of 4,4′-dihydroxy-α,α′-dimethyl benzalazine, the monofunctional dye fast yellow (FY), and a 50/50 mixture of sebacoyl and dodecanedioyl dichlorides. The weight-average molecular weights were estimated from inherent viscosity measurements to be between 6000–11,000 and the sodium sulfonate concentrations ranged from 0–18.4 meq/100 g polymer. Elemental analyses, however, indicated much higher molecular weights, which suggested that there was a distribution of chains with one, two, or no FY endgroups. The polymers were semicrystalline and melted at ca. 140°C to form nematic mesophases that were stable over a temperature range of ca. 80°C. They were thermally stable to about 350°C. The ionomeric nature of the polymers was confirmed by the presence of intermolecular associations in nonpolar solvents, as demonstrated by dilute solution viscosity measurements.     

主族元素取代的11-钨铜杂多配合物的合成、表征及性质研究

合成了ⅡA,ⅣA,ⅤA族元素为取代原子的3个系列钨铜杂多配合物.经ICP,TG曲线确定其化学式为K8[CuZ(OH2)W11O39].xH2O和K17,18[Z′(CuW11O39)2].xH2O(Z=Mg,Ca;Z′=Sr,Ba,Sn,Pb,Sb,Bi).通过TG-DTA,IR,XRD,XPS,183W-NMR等手段对合成配合物结构进行了表征,并对其进行了讨论.结果表明,新配合物具有典型的Keggin结构,且主族元素进入到配合物的骨架中.由于新配合物中CuⅡ具有顺磁性,导致XPS,183W-NMR的测试结果表现出特殊性;用循环伏安法测定了新配合物的电化学性质,表明均为可逆氧化还原过程,还对导电性和热稳定性进行了研究.     

Stabilization of p-block organoelement terminal hydroxides, thiols, and selenols requires newer synthetic strategies

Metal hydroxides represent a very interesting and highly useful class of compounds that have been known to chemists for a very long time. While alkali and alkaline earth metal hydroxides (s‐block) are commonplace chemicals in terms of their abundance and their use in a chemical laboratory as bases, the interest in Brønsted acidic molecular terminal hydroxides of p‐block elements, such as aluminum and silicon, has been of recent origin, with respect to the variety of applications these compounds can offer both in materials science and catalysis. Moreover, these systems are environmentally friendly, relative to the metal halides, owing to their ‐OH functionality (resembling that of water). Design and conceptualization of the corresponding terminal thiols, selenols, and tellurols (M? SH, M? SeH, and M? TeH) offer even more challenging problems to synthetic inorganic chemists. This concept summarizes some of the recent strategies developed to stabilize these otherwise very unstable species. The successful preparation of a number of silicon trihydroxides a few years back resulted in the generation of several model compounds for metal–silicates. The recent synthesis of unusual aluminum compounds such as RAl(OH)₂, RAl(SH)₂, and RAl(SeH)₂ with terminal EH (E=O, Se, or Se) groups is likely to change the ways in which some of the well‐known catalytic conversions are being carried out. The need for very flexible and innovative synthetic strategies to achieve these unusual compounds is emphasized in this concept.     

紫外分光光度法测定高山红景天根及其浸膏的有效成分

使用紫外分光光度法测定了高山红景天根不同部位及其浸膏中主要有效成分的含量.红景天甙、酪醇对照品溶液和供试品溶液在276nm处具有最大吸收峰,红景天甙对照品溶液的线性回归方程为A=0.00529c+0.00189,r=0.99997(n=8),线性范围为7.97～71.71mg/L,平均回收率为98.08%,RSD为2.60%(n=5).测得高山红景天原药材内层部分、外皮层部分和总体混合物部分主要有效成分(红景天甙和酪醇)的含量(以红景天甙计)分别为2.789%,2.385%和2.617%,其浸膏中主要有效成分的质量分数分别为6.384%,13.80%和6.700%.并用HPLC法验证了该法的准确性,结果表明,该法可用于红景天属植物原药材及其浸膏中主要有效成分的定量分析.